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Letters in Organic Chemistry
ISSN (Print): 1570-1786
ISSN (Online): 1875-6255
VOLUME: 10
ISSUE: 5
DOI: 10.2174/1570178611310050004      Price:  $58









L-Pyrrolidine-2-Carboxylic Acid-4-Hydrogen Sulfate (Supported on Silica Gel) as a New and Efficient Catalyst for Acylation of Alcohols, Phenols and Amines Under Solvent-Free Conditions

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Author(s): Maryam Hajjami, Arash Ghorbani-Choghamarani and Zahra Khani
Pages 324-329 (6)
Abstract:
In the present work, L-pyrrolidine-2-carboxylic acid-4-hydrogen sulfate, supported on silica gel was prepared and characterized by Mass spectroscopy, 1H NMR, 13CNMR, FT IR and elemental analysis (CHN) methods. This heterogenized catalyst can be used as an efficient catalyst for the acylation of alcohols, phenols, and amines with acetic anhydride under mild and solvent-free conditions. Simple work-up, stability of the catalyst, nontoxicity and good to high yields are the advantages of this work.
Keywords:
Acylation, L-pyrrolidine-2-carboxylic acid-4-hydrogen sulfate, Acetic anhydride, Alcohol, Phenol, Amine.
Affiliation:
Department of Chemistry, Faculty of Science, Ilam University, P.O. Box 69315516, Ilam, Iran.