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Current Green Chemistry

Editor-in-Chief

ISSN (Print): 2213-3461
ISSN (Online): 2213-347X

Catalyst- and Solvent-free Three-component Synthesis of Phosphane Sulfides

Author(s): Francisco Alonso and Yanina Moglie

Volume 1, Issue 2, 2014

Page: [87 - 93] Pages: 7

DOI: 10.2174/22133461114019990003

Price: $65

Abstract

The first three-component synthesis of phosphane sulfides from diphenylphosphane, elemental sulfur, and α,β-unsaturated carbonyl compounds is presented. Reactions proceed under solvent-free conditions in the absence of catalyst, providing the expected β-diphenylphosphorothioyl-functionalised products in moderate-to-high yields. Different experiments revealed that the process takes place through the in situ formation of diphenylphosphane sulfide and subsequent 1,4-addition to the substrate.

Keywords: Alkenes, catalyst-free reactions, conjugate addition, green chemistry, hydrothiophosphorylation, multicomponent reactions, phosphane sulfides, phosphines, solvent-free reactions, sulfides, α, β-unsaturated carbonyl compounds.


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