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Current Organic Synthesis
ISSN (Print): 1570-1794
ISSN (Online): 1875-6271
VOLUME: 11
ISSUE: 1
DOI: 10.2174/15701794113106660086









Glycosylated Metal Phthalocyanines

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Author(s): Michael Hanack, Goran Crucius, Mário J.F. Calvete and Thomas Ziegler
Pages 59-66 (8)
Abstract:
Methods for the synthesis of mono-, di-, and tetra-glycosylated phthalonitriles are described, which are key building blocks for the preparation of the corresponding glycosylated metal (mostly zinc) phthalocyanines. Than the preparation of symmetrically and unsymmetrically tetra- and octa-glycosylated zinc phthalocyanines in which the carbohydrate is attached either anomerically or via another one of its OH-groups to the phthalocyanine macrocycle is assessed.
Keywords:
Glycosylation, phthalocyanine, phthalonitrile.
Affiliation:
Institut fur Organische Chemie der Universitat Tubingen, Auf der Morgenstelle 18, 72076 Tubingen, Germany.