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Current Nutrition & Food Science

Editor-in-Chief

ISSN (Print): 1573-4013
ISSN (Online): 2212-3881

Short Communication

Rapid and Precise Discrimination between Pure and Adulterated Commercial Indian Honey Brands using FTIR Spectroscopy and Principal Component Analysis

Author(s): Bipin Singh* and Sanmitra Barman*

Volume 18, Issue 9, 2022

Published on: 02 June, 2022

Page: [780 - 784] Pages: 5

DOI: 10.2174/1573401318666220509214603

Price: $65

Abstract

Background: Four leading commercial Indian honey brands were investigated using FTIR spectroscopy and principal component analysis for rapid and accurate differentiation of pure, mildly adulterated, and highly adulterated honey brand samples. We examined the ability of PCA on second derivative of FTIR data to descriminate between the pure and adulterated commercial honey brands.

Methods: This study is the first to investigate commercial Indian honey brands using FTIR and PCA. We show that the top two principal components could easily descriminate between the pure and adulteraated honey brands.

Results: Hence such methods can investigate adulterations in bulk commercial honey brand samples where sophisticated instrumentations and facilities are not available.

Conclusion: Thus, the potential of FTIR and PCA can be further explored for detecting the presence of adulterations in bulk honey samples without much cost and effort.

Keywords: Contamination, adulteration detection, fourier-transform infrared spectroscopy, honey quality, chemometrics, food analytical methods.

Graphical Abstract
[1]
Se KW, Wahab RA, Yaacob SN, Ghoshal SK. Detection techniques for adulterants in honey: Challenges and recent trends. J Food Compos Anal 2019; 80: 16-32.
[http://dx.doi.org/10.1016/j.jfca.2019.04.001]
[2]
Kropf U, Golob T, Nečemer M M, et al. Carbon and nitrogen natural stable isotopes in Slovene honey: Adulteration and botanical and geographical aspects. J Agric Food Chem 2010; 58(24): 12794-803.
[http://dx.doi.org/10.1021/jf102940s] [PMID: 21087042]
[3]
Li S, Zhang X, Shan Y, et al. Qualitative and quantitative detection of honey adulterated with high-fructose corn syrup and maltose syrup by using near-infrared spectroscopy. Food Chem 2017; 218: 231-6.
[http://dx.doi.org/10.1016/j.foodchem.2016.08.105] [PMID: 27719903]
[4]
Khurana A, Dutta AP, Dhingra S. The honey trap: Investigation into the business of adulteration of honey. Down To Earth Magazine 2020; pp. 27-34.
[5]
Xue X, Wang Q, Li Y, et al. 2-acetylfuran-3-glucopyranoside as a novel marker for the detection of honey adulterated with rice syrup. J Agric Food Chem 2013; 61(31): 7488-93.
[http://dx.doi.org/10.1021/jf401912u] [PMID: 23844945]
[6]
Zábrodská B, Vorlová L. Adulteration of honey and available methods for detection–a review. Acta Vet Brno 2015; 83(10): 85-102.
[http://dx.doi.org/10.2754/avb201483S10S85]
[7]
Rios-Corripio MA, Rojas-López M, Delgado-Macuil R. Analysis of adulteration in honey with standard sugar solutions and syrups using attenuated total reflectance-fourier transform infrared spectroscopy and multivariate methods. CYTA J Food 2012; 10(2): 119-22.
[http://dx.doi.org/10.1080/19476337.2011.596576]
[8]
Wang J, Kliks MM, Jun S, Jackson M, Li QX. Rapid analysis of glucose, fructose, sucrose, and maltose in honeys from different geographic regions using fourier transform infrared spectroscopy and multivariate analysis. J Food Sci 2010; 75(2): C208-14.
[http://dx.doi.org/10.1111/j.1750-3841.2009.01504.x] [PMID: 20492227]
[9]
Gallardo-Velázquez T, Osorio-Revilla G, Zuñiga-de Loa M, Rivera-Espinoza Y. Application of FTIR-HATR spectroscopy and multivariate analysis to the quantification of adulterants in Mexican honeys. Food Res Int 2009; 42(3): 313-8.
[http://dx.doi.org/10.1016/j.foodres.2008.11.010]
[10]
Se KW, Ghoshal SK, Wahab RA, Ibrahim RKR, Lani MN. A simple approach for rapid detection and quantification of adulterants in stingless bees (Heterotrigona itama) honey. Food Res Int 2018; 105: 453-60.
[http://dx.doi.org/10.1016/j.foodres.2017.11.012] [PMID: 29433236]
[11]
Smith BC. Fundamentals of Fourier transform infrared spectroscopy. CRC Press 2011.
[http://dx.doi.org/10.1201/b10777]
[12]
Popovicheva O, Ivanov A, Vojtisek M. Functional factors of biomass burning contribution to spring aerosol composition in a megacity: Combined FTIR-PCA analyses. Atmosphere (Basel) 2020; 11(4): 319.
[http://dx.doi.org/10.3390/atmos11040319]
[13]
Whitbeck MR. Second derivative infrared spectroscopy. Appl Spectrosc 1981; 35(1): 93-5.
[http://dx.doi.org/10.1366/0003702814731851]

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