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Mini-Reviews in Organic Chemistry


ISSN (Print): 1570-193X
ISSN (Online): 1875-6298

A Convenient Access to the Piperidine Ring by Cyclization of Allylsilyl Substituted N- cyliminium and Iminium Ions: Application to the Synthesis of Piperidine Alkaloids.

Author(s): R. Remuson and Y. Gelas-Mialhe

Volume 5, Issue 3, 2008

Page: [193 - 208] Pages: 16

DOI: 10.2174/157019308785161701

Price: $65


This review relates a new access to the piperidine ring by intramolecular cyclization of acyl iminium and iminium ions substituted by an allylsilyl side chain as an internal Π-nucleophile. This methodology was applied to the synthesis of piperidine alkaloids

Keywords: Piperidine, iminium ions, N-acyliminium ions, indolizidine, quinolizidine

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