Abstract
A series of new ester-substituted alkoxysilanes has been prepared. These bifunctional silanes were gently synthesized via hydrosilylation of carbon-carbon double bond of commercially available unsaturated esters in the presence of Karstedt’s catalyst. All products were isolated and fully characterized by NMR and IR spectroscopy. The synthesized derivatives can be further applied to obtain the siloxane network on the silica surface.
Keywords: Hydrosilylation, silanes, silyl ethers, alkoxysilanes, allyl esters, homogeneous catalysis, platinum.
Current Organic Chemistry
Title:The Synthesis of Novel Bifunctional Silanes Containing Ester Groups
Volume: 22 Issue: 24
Author(s): Karolina Bartkowiak, Giuseppe Consiglio and Grzegorz Hreczycho*
Affiliation:
- Faculty of Chemistry, Adam Mickiewicz University in Poznan, Umultowska 89b, 61-614 Poznan,Poland
Keywords: Hydrosilylation, silanes, silyl ethers, alkoxysilanes, allyl esters, homogeneous catalysis, platinum.
Abstract: A series of new ester-substituted alkoxysilanes has been prepared. These bifunctional silanes were gently synthesized via hydrosilylation of carbon-carbon double bond of commercially available unsaturated esters in the presence of Karstedt’s catalyst. All products were isolated and fully characterized by NMR and IR spectroscopy. The synthesized derivatives can be further applied to obtain the siloxane network on the silica surface.
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Cite this article as:
Bartkowiak Karolina , Consiglio Giuseppe and Hreczycho Grzegorz *, The Synthesis of Novel Bifunctional Silanes Containing Ester Groups, Current Organic Chemistry 2018; 22 (24) . https://dx.doi.org/10.2174/1385272822666181024125042
DOI https://dx.doi.org/10.2174/1385272822666181024125042 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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