Abstract
Supported catalysts have become valuable tools for simplified product isolation and catalyst recycling. The common method is covalent attachment to a solid support. An alternative strategy is to immobilize catalysts by non-covalent bonding through hydrogen bridges, ionic, hydrophobic or fluorous interactions. Compared to covalent attachment, such non-covalent approaches increase the flexibility in the choice of the support-material, reaction conditions and work-up strategies. Numerous catalytic reactions employing one of these non-covalent fixation strategies have meanwhile appeared in the literature.
Keywords: supported catalysts, non-covalent immobilization, heterogeneous catalysis
Combinatorial Chemistry & High Throughput Screening
Title: Application of Non-Covalently Solid-Phase Bound Catalysts
Volume: 6 Issue: 7
Author(s): F. Michalek, J. Horn, C. C. Tzschucke and W. Bannwarth
Affiliation:
Keywords: supported catalysts, non-covalent immobilization, heterogeneous catalysis
Abstract: Supported catalysts have become valuable tools for simplified product isolation and catalyst recycling. The common method is covalent attachment to a solid support. An alternative strategy is to immobilize catalysts by non-covalent bonding through hydrogen bridges, ionic, hydrophobic or fluorous interactions. Compared to covalent attachment, such non-covalent approaches increase the flexibility in the choice of the support-material, reaction conditions and work-up strategies. Numerous catalytic reactions employing one of these non-covalent fixation strategies have meanwhile appeared in the literature.
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Cite this article as:
Michalek F., Horn J., Tzschucke C. C. and Bannwarth W., Application of Non-Covalently Solid-Phase Bound Catalysts, Combinatorial Chemistry & High Throughput Screening 2003; 6 (7) . https://dx.doi.org/10.2174/138620703771981250
DOI https://dx.doi.org/10.2174/138620703771981250 |
Print ISSN 1386-2073 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5402 |
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